A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes

A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2017, Volume: 27, Number: 5, Pages: 464-465 Pages count : 2 DOI: 10.1016/j.mencom.2017.09.011

Authors

Filyakova Vera I. ¹ , Boltachova Nadezhda S. ¹ , Pervova Marina G. ¹ , Palysaeva Nadezhda V. ² , Slepukhin Pavel A. ¹ , Sheremetev Aleksei B. ² , Charushin Valery N. ¹

Affiliations

1	I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 620990 Ekaterinburg, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A convenient direct synthesis of 1-aryl-3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes from the corresponding lithium 3-(polyfluoroalkyl)- 1,3-diketonates has been elaborated using sodium nitrite/acetic acid system under very mild conditions. The molecular structure of 4,4-difluoro-1-phenylbutane- 1,2,3-trione 2-oxime has been determined by X-ray crystallography.

Filyakova V.I. , Boltachova N.S. , Pervova M.G. , Palysaeva N.V. , Slepukhin P.A. , Sheremetev A.B. , Charushin V.N.
A simple and efficient synthesis of 3-(polyfluoroalkyl)propane-1,2,3-trione 2-oximes
Mendeleev Communications. 2017. V.27. N5. P.464-465. DOI: 10.1016/j.mencom.2017.09.011 WOS Scopus OpenAlex

≡ Web of science:	WOS:000413618800011
≡ Scopus:	2-s2.0-85030126120
≡ OpenAlex:	W2759681005