Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9 H ,9 ’H -bifluorene-9,9 ’- diol

Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9 H ,9 ’H -bifluorene-9,9 ’- diol Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2017, Volume: 27, Number: 6, Pages: 580-582 Pages count : 3 DOI: 10.1016/j.mencom.2017.11.014

Authors

Mendkovich Andrey S. ¹ , Syroeshkin Mikhail A. ¹ , Mitina Kristina R. ¹ , Mikhailov Mikhail N. ¹ , Gultyai Vadim P. ¹ , Pechennikov Valery M. ²

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	I. M. Sechenov First Moscow State Medical University, 119991 Moscow, Russian Federation

Cyclic voltammetry, digital simulation and quantum chemical methods were applied to study the electroreduction mechanism of vicinal hydroxyl derivatives using 9H,9’H-bifluorene- 9,9’-diol as an example. Unlike the case of fluoren-9-ol, dissociation of the C9–C9’ bond rather than the C9–OH one occurs in radical anion of the substrate, similarly to that in radical cations formed upon oxidation of vicinal hydroxyl derivatives.

Mendkovich A.S. , Syroeshkin M.A. , Mitina K.R. , Mikhailov M.N. , Gultyai V.P. , Pechennikov V.M.
Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9 H ,9 ’H -bifluorene-9,9 ’- diol
Mendeleev Communications. 2017. V.27. N6. P.580-582. DOI: 10.1016/j.mencom.2017.11.014 WOS Scopus OpenAlex

Web of science:	WOS:000418983900014
Scopus:	2-s2.0-85034806510
OpenAlex:	W2769717729

DB	Citing
OpenAlex	9
Scopus	7
Web of science	7