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Photocyclization of diarylethenes: the effect of imidazole on the oxidative photodegradation process Научная публикация

Журнал Photochemical & Photobiological Sciences
ISSN: 1474-9092 , E-ISSN: 1474-905X
Вых. Данные Год: 2019, Том: 18, Номер: 5, Страницы: 1101-1109 Страниц : 9 DOI: 10.1039/c8pp00507a
Авторы Zakharov A.V. 1 , Lvov A.G. 1 , Rostovtseva I.A. 2 , Metelitsa A.V. 2 , Chernyshev A.V. 2 , Krayushkin M.M. 1 , Yadykov A.V. 1 , Shirinian V.Z. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2 Institute of Physical and Organic Chemistry, Southern Federal University, Rostov on Don, Russian Federation

Реферат: We have studied the photoreaction of 1,2-diarylethenes under aerobic conditions in the presence of various amines to prevent side processes promoted by singlet oxygen. It has been found that the most amines quite effectively deactivate processes associated with singlet oxygen, but primary and secondary amines unlike tertiary ones, react with substrates resulting in various side products. Among the studied amines, the most effective additive for preventing side processes, including those associated with singlet oxygen is imidazole, which is practically not consumed in photoreaction. It was shown that imidazole can also prevents the photodegradation of organic photochromes in solutions. The results obtained can be used in various branches of science, technology and medicine to improve the photostability of photosensitive organics (dyes).
Библиографическая ссылка: Zakharov A.V. , Lvov A.G. , Rostovtseva I.A. , Metelitsa A.V. , Chernyshev A.V. , Krayushkin M.M. , Yadykov A.V. , Shirinian V.Z.
Photocyclization of diarylethenes: the effect of imidazole on the oxidative photodegradation process
Photochemical & Photobiological Sciences. 2019. V.18. N5. P.1101-1109. DOI: 10.1039/c8pp00507a WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000468060100015
Scopus: 2-s2.0-85065471690
OpenAlex: W2913047849
Цитирование в БД:
БД Цитирований
OpenAlex 23
Scopus 21
Web of science 21
Альметрики: