Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst

Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2019, Volume: 21, Number: 11, Pages: 4271-4274 Pages count : 4 DOI: 10.1021/acs.orglett.9b01450

Authors

Supranovich Vyacheslav I. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation

A method for the radical addition toward N-tosylimines based on light promoted C–H activation by tetrabutylammonium decatungstate is described. The reaction proceeds under irradiation using 400 nm light emitting diodes in conventional glassware. The method can be applied for alkylations (cycloalkanes, ethers, dimethylformamide) and acylation (primary aliphatic aldehydes) of both aromatic and aliphatic N-tosylimines.

Supranovich V.I. , Levin V.V. , Dilman A.D.
Radical Addition to N-Tosylimines via C–H Activation Induced by Decatungstate Photocatalyst
Organic Letters. 2019. V.21. N11. P.4271-4274. DOI: 10.1021/acs.orglett.9b01450 WOS Scopus OpenAlex

Web of science:	WOS:000471212100084
Scopus:	2-s2.0-85066917451
OpenAlex:	W2946280130

DB	Citing
OpenAlex	64
Scopus	62