Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides

Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2023, Volume: 33, Number: 4, Pages: 461-462 Pages count : 2 DOI: 10.1016/j.mencom.2023.06.006

Authors

Budkova Alexandra V. ^1,2 , Merkulov Vladislav G. ^1,2 , Ivanov Roman E. ² , Zharkov Mikhail N. ² , Kuchurov Ilya V. ² , Zlotin Sergei G. ²

Affiliations

1	D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A concise safe approach for selective nitration and nitroxylation of tert-alkanes, in particular adamantane, and tert-alkyl bromides utilizing NO2 in supercritical CO2 medium has been established. Major reaction products were tert-alkyl nitro compounds and tert-alkyl nitrates depending on the reaction conditions.

Budkova A.V. , Merkulov V.G. , Ivanov R.E. , Zharkov M.N. , Kuchurov I.V. , Zlotin S.G.
Application of NO2/supercritical CO2 system for safe and selective nitration of adamantanes and tertiary alkyl bromides
Mendeleev Communications. 2023. V.33. N4. P.461-462. DOI: 10.1016/j.mencom.2023.06.006 WOS Scopus OpenAlex

Web of science:	WOS:001043965000001
Scopus:	2-s2.0-85166584616
OpenAlex:	W4384501577

DB	Citing
OpenAlex	3
Scopus	4
Web of science	2