Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions

Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions Full article

Journal

Molecular Catalysis
ISSN: 2468-8231 , E-ISSN: 2468-8274

Output data

Year: 2021, Volume: 502, Article number : 111398, Pages count : DOI: 10.1016/j.mcat.2021.111398

Authors

Greish Alexander A. ¹ , Barkova Alexandra P. ¹ , Finashina Elena D. ¹ , Salmi Tapio O. ² , Kustov Leonid M. ^1,3,4

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991, Moscow, Russia
2	Abo Akademi University, Turku, Biskopsgatan 8, Finland
3	Department of Chemistry, Moscow State University, Leninskie Gory 1, Bldg. 3, 119991, Moscow, Russia
4	National University of Science and Technology MISiS, Leninsky Prosp. 4, 119991, Moscow, Russia

A Re2O7-B2O3/Al2O3 catalyst was demonstrated to reveal significant activity in cyclohexene dimerization into 1-cyclohexenylcyclohexane with a total yield of 95 % and a selectivity close to 100 % in the batch mode at 75−80°C and atmospheric pressure.

Greish A.A. , Barkova A.P. , Finashina E.D. , Salmi T.O. , Kustov L.M.
Selective dimerization of cyclohexene over a Re2O7-B2O3/Al2O3 catalyst under mild conditions
Molecular Catalysis. 2021. V.502. 111398 . DOI: 10.1016/j.mcat.2021.111398 WOS Scopus OpenAlex

Web of science:	WOS:000649342100024
Scopus:	2-s2.0-85099193819
OpenAlex:	W3120995460

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