Radical Silyldifluoromethylation of Electron-Deficient Alkenes

Radical Silyldifluoromethylation of Electron-Deficient Alkenes Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2017, Volume: 19, Number: 12, Pages: 3215-3218 Pages count : 4 DOI: 10.1021/acs.orglett.7b01334

Authors

Supranovich Vyacheslav I. ¹ , Levin Vitalij V. ¹ , Struchkova Marina I. ¹ , Korlyukov Alexander A. ² , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry , Leninsky prosp. 47, 119991 Moscow, Russian Federation.
2	A.N. Nesmeyanov Institute of Organoelement Compounds, Vavilov str. 28, 119991 Moscow, Russian Federation

A reaction of bromo- and iododifluoromethyl-substituted silanes with electron-deficient alkenes in the presence of an N-heterocyclic carbene borane complex is described. The reaction is performed under irradiation with light-emitting diodes and proceeds via a radical chain mechanism. The resulting products, the functionalized silicon reagents, can undergo chemoselective transformations involving either the silyldifluoromethyl fragment or the functional group.

Supranovich V.I. , Levin V.V. , Struchkova M.I. , Korlyukov A.A. , Dilman A.D.
Radical Silyldifluoromethylation of Electron-Deficient Alkenes
Organic Letters. 2017. V.19. N12. P.3215-3218. DOI: 10.1021/acs.orglett.7b01334 WOS Scopus OpenAlex

Web of science:	WOS:000403854300045
Scopus:	2-s2.0-85020870269
OpenAlex:	W2620132801

DB	Citing
OpenAlex	52
Scopus	43
Web of science	48