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Double electrooxidative C–H functionalization of (het)arenes with thiocyanate and 4-nitropyrazolate ions Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 2019, Volume: 29, Number: 3, Pages: 334-336 Pages count : 3 DOI: 10.1016/j.mencom.2019.05.032
Authors Yaubasarova Rauza R. 1 , Kokorekin Vladimir A. 2,3,1 , Ramenskaya Galina V. 2 , Petrosyan Vladimir A. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2 I. M. Sechenov First Moscow State Medical University, 119991 Moscow, Russian Federation
3 All-Russian Research Institute of Phytopathology, 143050 Bol'shiye Vyazemy, Moscow Region, Russian Federation

Abstract: The double anodic C–H functionalization of N-methyl-1H-pyrrole and N,N-dimethylaniline using both thiocyanate and 4-nitro-1H-pyrazolate ions as nucleophiles has been accomplished for the first time. The mild reaction conditions and considerable pharmacological activity of the target products make such C–S and C–N coupling strategy to be highly attractive for further applications.
Cite: Yaubasarova R.R. , Kokorekin V.A. , Ramenskaya G.V. , Petrosyan V.A.
Double electrooxidative C–H functionalization of (het)arenes with thiocyanate and 4-nitropyrazolate ions
Mendeleev Communications. 2019. V.29. N3. P.334-336. DOI: 10.1016/j.mencom.2019.05.032 WOS Scopus OpenAlex
Identifiers:
≡ Web of science: WOS:000472703800032
≡ Scopus: 2-s2.0-85066858359
≡ OpenAlex: W2956047744
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