Selective synthesis of cyclic triperoxides from 1,1′-dihydroperoxydi(cycloalkyl)peroxides and acetals using SnCl4

Selective synthesis of cyclic triperoxides from 1,1′-dihydroperoxydi(cycloalkyl)peroxides and acetals using SnCl4 Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2019, Volume: 68, Number: 6, Pages: 1289-1292 Pages count : 4 DOI: 10.1007/s11172-019-2555-7

Authors

Radulov P.S. ^1,2 , Belyakova Yu.Yu. ¹ , Demina A.A. ³ , Nikishin G.I. ¹ , Yaremenko I.A. ^1,4,2 , Terent’ev A.O. ^1,4,2

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation
2	All-Russia Research Institute for Phytopathology, 5 ul. Institut, Bolshie Vyazyomy, Odintsovo District, 143050 Мoscow Region, Russian Federation.
3	M. V. Lomonosov Moscow State University, 1-3 Leninskiye Gory, 119991 Moscow, Russian Federation
4	D. I. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047 Moscow, Russian Federation

A method for the synthesis of 1,2,4,5,7,8-hexaoxonanes by the reaction of 1,1′-dihydroperoxydi(cycloalkyl)peroxides with acetals using SnCl4 has been developed. For the first time, it was shown that SnCl4 can serve as an effective reagent for the synthesis of cyclic organic peroxides. The proposed method allows obtaining 9-membered cyclic triperoxides selectively and in the yields of up to 90% based on the isolated product.

Radulov P.S. , Belyakova Y.Y. , Demina A.A. , Nikishin G.I. , Yaremenko I.A. , Terent’ev A.O.
Selective synthesis of cyclic triperoxides from 1,1′-dihydroperoxydi(cycloalkyl)peroxides and acetals using SnCl4
Russian Chemical Bulletin. 2019. V.68. N6. P.1289-1292. DOI: 10.1007/s11172-019-2555-7 WOS Scopus OpenAlex

≡ Web of science:	WOS:000473522800024
≡ Scopus:	2-s2.0-85068611769
≡ OpenAlex:	W2955028443