CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions

CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2019, Volume: 29, Number: 4, Pages: 382-384 Pages count : 3 DOI: 10.1016/j.mencom.2019.07.007

Authors

Pokusaeva Yana A. ¹ , Koklin Aleksey E. ¹ , Lunin Valery V. ^2,1 , Bogdan Victor I. ^2,1

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

New catalysts FeK/Sibunit and FeCuK/Sibunit were prepared and applied for the CO2 hydrogenation in the temperature range of 250–400 °C and under the pressures of 1, 20 and 85 atm. The reverse water gas shift reaction prevailed under the atmospheric pressure (i.e., CO2 was selectively converted into CO), while the formation of C1–C12 hydrocarbons occurred under the increased pressures. The Cu-containing catalyst exhibited the higher activity and selectivity towards C1–C12 hydrocarbons.

Pokusaeva Y.A. , Koklin A.E. , Lunin V.V. , Bogdan V.I.
CO2 hydrogenation on Fe-based catalysts doped with potassium in gas phase and under supercritical conditions
Mendeleev Communications. 2019. V.29. N4. P.382-384. DOI: 10.1016/j.mencom.2019.07.007 WOS Scopus OpenAlex

≡ Web of science:	WOS:000484653500007
≡ Scopus:	2-s2.0-85070612040
≡ OpenAlex:	W2967120178