Azasydnone – novel “green” building block for designing high energetic compounds

Azasydnone – novel “green” building block for designing high energetic compounds Научная публикация

Журнал

Journal of Materials Chemistry A
ISSN: 2050-7488 , E-ISSN: 2050-7496

Вых. Данные

Год: 2018, Том: 6, Номер: 38, Страницы: 18669-18676 Страниц : 8 DOI: 10.1039/c8ta06895j

Авторы

Dalinger Igor L. ¹ , Serushkina Olga V. ¹ , Muravyev Nikita V. ² , Meerov Dmitry B. ² , Miroshnichenko Evgeniy A. ² , Kon'kova Tatyana S. ² , Suponitsky Kyrill Yu. ³ , Vener Mikhail V. ⁴ , Sheremetev Aleksei B. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 119991, Russian Federation
3	Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow 119991, Russian Federation
4	Mendeleev University of Chemical Technology, Moscow 125047, Russian Federation

The discovery of novel explosophoric building blocks for the construction of energetic compounds is extremely rare. Here, based on the comparative experimental properties and computational analysis of compounds where nitroaryl backbones were bonded with various nitrogen/oxygen-rich groups, it is shown that compounds having the azasydnone group possess higher density, detonation performance and thermal stability than their corresponding nitro, azido and tetrazole-analogs. All of these properties, as well as the oxygen balanced content of the “green” nitrogen rich endothermic unit make them an attractive explosophoric building block in the field of energetic materials chemistry.

Dalinger I.L. , Serushkina O.V. , Muravyev N.V. , Meerov D.B. , Miroshnichenko E.A. , Kon'kova T.S. , Suponitsky K.Y. , Vener M.V. , Sheremetev A.B.
Azasydnone – novel “green” building block for designing high energetic compounds
Journal of Materials Chemistry A. 2018. V.6. N38. P.18669-18676. DOI: 10.1039/c8ta06895j WOS Scopus OpenAlex

≡ Web of science:	WOS:000451380800038
≡ Scopus:	2-s2.0-85054371773
≡ OpenAlex:	W2890529459