In Situ Generated Magnesium Cyanide as an Efficient Reagent for Nucleophilic Cyanation of Nitrosoalkenes and Parent Nitronates

In Situ Generated Magnesium Cyanide as an Efficient Reagent for Nucleophilic Cyanation of Nitrosoalkenes and Parent Nitronates Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2019, Volume: 2019, Number: 9, Pages: 1888-1892 Pages count : 5 DOI: 10.1002/ejoc.201801761

Authors

Ushakov Pavel Yu. ^1,2 , Tabolin Andrey A. ¹ , Ioffe Sema L. ¹ , Sukhorukov Alexey Yu. ^1,3

Affiliations

1	Laboratory of Functional Organic Compounds, N. D. Zelinsky Institute of Organic Chemistry, Leninsky prospect, 47, 119991 Moscow, Russia
2	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
3	Plekhanov Russian University of Economics, Stremyanny per. 36, 117997 Moscow, Russia

In situ generated magnesium cyanide [NaCN/Mg(ClO4)2] is suggested as a convenient, readily available, non-volatile and organic-soluble reagent for hydrocyanation reactions. It was successfully used for nucleophilic cyanation of nitrosoalkenes, nitronates, as well as other typical π-electrophiles, such as imines, α,β-unsaturated ketones, alkylidenemalonates and azoalkenes.

Ushakov P.Y. , Tabolin A.A. , Ioffe S.L. , Sukhorukov A.Y.
In Situ Generated Magnesium Cyanide as an Efficient Reagent for Nucleophilic Cyanation of Nitrosoalkenes and Parent Nitronates
European Journal of Organic Chemistry. 2019. V.2019. N9. P.1888-1892. DOI: 10.1002/ejoc.201801761 WOS Scopus OpenAlex

Web of science:	WOS:000460580000004
Scopus:	2-s2.0-85060513952
OpenAlex:	W2907213221

DB	Citing
OpenAlex	14
Scopus	14
Web of science	14