(2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione)

(2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione) Full article

Journal

Molbank
ISSN: 1422-8599

Output data

Year: 2024, Volume: 2024, Number: 1, Article number : M1764, Pages count : DOI: 10.3390/m1764

Authors

Vlasova Tatiana S. ^1,2 , Romanova Yulia E. ¹ , Taidakov Ilya V. ^1,2 , Paveliev Stanislav A. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia
2	P.N. Lebedev Physical Institute, Russian Academy of Sciences, 53 Leninsky Prospekt, 119991 Moscow, Russia

In this work, the title compound was synthesized via the reaction of an aryl-substituted pyrazole with potassium tetrachloroplatinate, followed by the reaction of the postulated intermediate chloro-bridged dimer with a pyrazole-containing 1,3-diketonate ligand. The structure of the synthesized complex was established by 1H, 13C NMR spectroscopy and mass spectrometry. According to UV-Vis spectrometry studies, the obtained complex exhibits green fluorescence with a maximum at 514 nm. Based on cyclic voltammetry studies, the HOMO, LUMO and band gap values were calculated.

Vlasova T.S. , Romanova Y.E. , Taidakov I.V. , Paveliev S.A.
(2-[4-Methylpyrazol-1-yl]phenyl)platinum(II) (1,3-bis[1-methyl-1H-pyrazol-4-yl]propane-1,3-dione)
Molbank. 2024. V.2024. N1. M1764 . DOI: 10.3390/m1764 WOS Scopus OpenAlex

≡ Web of science:	WOS:001193397100001
≡ Scopus:	2-s2.0-85189181822
≡ OpenAlex:	W4391232222