Photoredox Fluoroalkylation of Arylidene and Alkylidene Amidrazones

Photoredox Fluoroalkylation of Arylidene and Alkylidene Amidrazones Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2020, Volume: 2020, Number: 3, Pages: 393-396 Pages count : 4 DOI: 10.1002/ejoc.201901672

Authors

Supranovich Vyacheslav I. ¹ , Chernov Grigory N. ^2,1 , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2	Department of Chemistry, Moscow State University, Leninskie Gory 1-3, 119991 Moscow, Russian Federation

A method for the photoredox fluoroalkylation of the C–H bond of azomethine compounds obtained from condensation of aldehydes and N-methylpyrrolidinone-derived amidrazones is described. The reactions are promoted with a carbazole-based organic photocatalyst under blue light irradiation. The ability of the cyclic nitrogen to stabilize a nitrogen-centered radical is believed to be a key factor responsible for the reaction efficiency.

Supranovich V.I. , Chernov G.N. , Levin V.V. , Dilman A.D.
Photoredox Fluoroalkylation of Arylidene and Alkylidene Amidrazones
European Journal of Organic Chemistry. 2020. V.2020. N3. P.393-396. DOI: 10.1002/ejoc.201901672 WOS Scopus OpenAlex

Web of science:	WOS:000509416900014
Scopus:	2-s2.0-85076765297
OpenAlex:	W2991805844

DB	Citing
OpenAlex	10
Scopus	8