Effect of isomerization on the performance of aromatic hydrogen storage systems possessing different condensation extents

Effect of isomerization on the performance of aromatic hydrogen storage systems possessing different condensation extents Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2019, Volume: 29, Number: 1, Pages: 25-28 Pages count : 4 DOI: 10.1016/j.mencom.2019.01.007

Authors

Kustov Leonid M. ^1,2,3 , Kalenchuk Alexander N. ^1,2 , Dunaev Sergei F. ² , Bogdan Victor I. ^1,2

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
3	National University of Science and Technology ‘MISIS’, 119991 Moscow, Russian Federation

The influence of structural differences in cis- and trans-conformer molecules of ortho-, meta- and para-isomers of perhydroterphenyl and decalin on the hydrogen release in hydrogen storage systems was estimated for the Pt/C catalyst in a flow regime. The structural differences between the cis- and trans-conformers of perhydroterphenyl did not significantly affect the reactivity of its ortho-, meta- and para-isomers. In the case of decalin, the decrease in the volume of released hydrogen due to the conversion of its cis-isomer into the less active trans-form was clearly demonstrated.

Kustov L.M. , Kalenchuk A.N. , Dunaev S.F. , Bogdan V.I.
Effect of isomerization on the performance of aromatic hydrogen storage systems possessing different condensation extents
Mendeleev Communications. 2019. V.29. N1. P.25-28. DOI: 10.1016/j.mencom.2019.01.007 WOS Scopus OpenAlex

≡ Web of science:	WOS:000460711400007
≡ Scopus:	2-s2.0-85061607994
≡ OpenAlex:	W2913398850