Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane

Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2017, Volume: 66, Number: 6, Pages: 1066-1073 Pages count : 8 DOI: 10.1007/s11172-017-1855-z

Authors

Luk´yanov O.A. ¹ , Shlykova N.I. ¹ , Pokhvisneva G.V. ¹ , Ternikova T.V. ¹ , Nikitin S.V. ¹ , Smirnov G.A. ¹ , Nelubina Yu.V. ² , Dorovatovskii P.V. ³ , Kon´kova T.S. ⁴ , Murav´yov N.V. ⁴ , Pivkina A.N. ⁴

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russian Federation
3	National Research Center “Kurchatov Institute”, Moscow, Russian Federation
4	N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

The key steps of the synthesis of two high energy compounds, namely, 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane, were optimized. Their enthalpy of formation, density, impact and friction sensitivity, and thermal stability were experimentally determined.

Luk´yanov O.A. , Shlykova N.I. , Pokhvisneva G.V. , Ternikova T.V. , Nikitin S.V. , Smirnov G.A. , Nelubina Y.V. , Dorovatovskii P.V. , Kon´kova T.S. , Murav´yov N.V. , Pivkina A.N.
Optimization of the key steps of synthesis and study of the fundamental physicochemical properties of high energy compounds — 4-(2,2,2-trinitroethyl)-2,6,8,10,12-pentanitrohexaazaisowurtzitane and 4,10-bis(2,2,2-trinitroethyl)-2,6,8,12-tetranitrohexaazaisowurtzitane
Russian Chemical Bulletin. 2017. V.66. N6. P.1066-1073. DOI: 10.1007/s11172-017-1855-z WOS Scopus OpenAlex

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