Diphenylacetylene hydrogenation on a PdAg /Al 2 O 3 single-atom catalyst: an experimental and DFT study

Diphenylacetylene hydrogenation on a PdAg /Al 2 O 3 single-atom catalyst: an experimental and DFT study Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2017, Volume: 27, Number: 6, Pages: 615-617 Pages count : 3 DOI: 10.1016/j.mencom.2017.11.026

Authors

Rassolov Aleksandr V. ¹ , Krivoruchenko Dmitry S. ¹ , Medvedev Michael G. ¹ , Mashkovsky Igor S. ¹ , Stakheev Aleksandr Yu. ¹ , Svitanko Igor V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The hydrogenation of diphenylacetylene (DPA) on palladium–silver catalysts with a single-atom structure was investigated. It has been shown experimentally that the reaction rate of alkene to alkane hydrogenation is substantially lower than the rate of DPA semi-hydrogenation. The kinetic barriers of all stages of hydrogenation were calculated by the DFT method.

Rassolov A.V. , Krivoruchenko D.S. , Medvedev M.G. , Mashkovsky I.S. , Stakheev A.Y. , Svitanko I.V.
Diphenylacetylene hydrogenation on a PdAg /Al 2 O 3 single-atom catalyst: an experimental and DFT study
Mendeleev Communications. 2017. V.27. N6. P.615-617. DOI: 10.1016/j.mencom.2017.11.026 WOS Scopus OpenAlex

Web of science:	WOS:000418983900026
Scopus:	2-s2.0-85034835343
OpenAlex:	W2769826061

DB	Citing
OpenAlex	19
Scopus	17
Web of science	17