Oxidative dehydrogenation of ethane over a Mo–V–Nb–Te–O mixed-oxide catalyst in a cyclic mode

Oxidative dehydrogenation of ethane over a Mo–V–Nb–Te–O mixed-oxide catalyst in a cyclic mode Full article

Journal

Kinetics and Catalysis
ISSN: 1608-3210 , E-ISSN: 0023-1584

Output data

Year: 2017, Volume: 58, Number: 2, Pages: 156-160 Pages count : 5 DOI: 10.1134/s0023158417020094

Authors

Mishanin I.I. ¹ , Kalenchuk A.N. ^1,2 , Maslakov K.I. ¹ , Lunin V.V. ^1,2 , Koklin A.E. ² , Finashina E.D. ² , Bogdan V.I. ^2,1

Affiliations

1	Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia
2	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119911, Russia

The oxidative dehydrogenation of ethane (ODE) into ethylene over a Mo–V–Nb–Te–O mixedoxide catalyst in a cyclic mode with alternate feeding of ethane and air has been investigated. The amount of oxide-phase oxygen involved in the reaction has been estimated by titrating the oxygen of the active phase of the catalyst with ethane. The reactivity of this oxygen increases with an increasing temperature. The amount active oxygen involved in ODE at 360–400°C is 0.2–0.6 mmol/g.

Mishanin I.I. , Kalenchuk A.N. , Maslakov K.I. , Lunin V.V. , Koklin A.E. , Finashina E.D. , Bogdan V.I.
Oxidative dehydrogenation of ethane over a Mo–V–Nb–Te–O mixed-oxide catalyst in a cyclic mode
Kinetics and Catalysis. 2017. V.58. N2. P.156-160. DOI: 10.1134/s0023158417020094 WOS Scopus OpenAlex

Web of science:	WOS:000399710500007
Scopus:	2-s2.0-85017611816
OpenAlex:	W2606382485

DB	Citing
OpenAlex	16
Scopus	16
Web of science	15