Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments

Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2018, Volume: 28, Number: 6, Pages: 603-605 Pages count : 3 DOI: 10.1016/j.mencom.2018.11.013

Authors

Mashkovsky Igor S. ¹ , Smirnova Nadezhda S. ¹ , Markov Pavel V. ¹ , Baeva Galina N. ¹ , Bragina Galina O. ¹ , Bukhtiyarov Andrey V. ² , Prosvirin Igor P. ² , Stakheev Aleksandr Yu. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation

The in situ DRIFT-CO and XPS data demonstrated that the mild oxidation of PdIn intermetallic nanoparticles results in the partial oxidation of an In component and the trans-formation of isolated Pd1 sites to Pdn multiatomic ones thus enhancing PdIn activity in the liquid-phase hydrogenation of diphenylacetylene without sacrificing the alkene selectivity.

Mashkovsky I.S. , Smirnova N.S. , Markov P.V. , Baeva G.N. , Bragina G.O. , Bukhtiyarov A.V. , Prosvirin I.P. , Stakheev A.Y.
Tuning the surface structure and catalytic performance of PdIn/Al2O3 in selective liquid-phase hydrogenation by mild oxidative-reductive treatments
Mendeleev Communications. 2018. V.28. N6. P.603-605. DOI: 10.1016/j.mencom.2018.11.013 WOS Scopus OpenAlex

Web of science:	WOS:000455070900013
Scopus:	2-s2.0-85057578987
OpenAlex:	W2905423982

DB	Citing
OpenAlex	33
Scopus	25
Web of science	23