Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures

Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures Full article

Journal

Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1555-6239

Output data

Year: 2023, Volume: 63, Number: 4, Pages: 468-476 Pages count : 9 DOI: 10.1134/s0965544123030118

Authors

Kazakov A.I. ¹ , Yanovskiy L.S. ² , Tomilov Yu.V. ³ , Molokanov A.A. ² , Plishkin N.A. ¹ , Lempert D.B. ¹ , Varlamova N.I. ¹

Affiliations

1	Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Russia
2	Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432, Chernogolovka, Russia
3	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

The kinetics of thermal decomposition of cage hydrocarbons, specifically exo-tricyclo[5.2.1.02.6]decane (exo-TCD) and exo,endo-tetracyclo[5.3.1.02,6.08,10]undecane (TCU-1, a monocyclopropanated analog of exo-TCD), as well as their mixture (1 : 3 w/w) has been investigated. These compounds were compared in terms of thermal stability. The molar concentrations of the resultant gaseous products were determined experimentally. The equilibrium composition of the decomposition products was quantified, and the thermal effects of the thermal decomposition under thermodynamic and kinetic reaction control were identified.

Kazakov A.I. , Yanovskiy L.S. , Tomilov Y.V. , Molokanov A.A. , Plishkin N.A. , Lempert D.B. , Varlamova N.I.
Thermal Decomposition of Synthetic Cage Hydrocarbons and Their Mixtures
Petroleum Chemistry. 2023. V.63. N4. P.468-476. DOI: 10.1134/s0965544123030118 WOS Scopus OpenAlex

≡ Web of science:	WOS:001020333700004
≡ Scopus:	2-s2.0-85162856020
≡ OpenAlex:	W4382049713