Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction Full article
Journal |
Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X |
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Output data | Year: 2018, Volume: 54, Number: 18, Pages: 2236-2239 Pages count : 4 DOI: 10.1039/c8cc00245b | ||||||||||
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Abstract:
A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C–B bond occurs via single electron reduction by a Cu(I) photocatalyst activated by visible light.
Cite:
Smirnov V.O.
, Maslov A.S.
, Kokorekin V.A.
, Korlyukov A.A.
, Dilman A.D.
Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction
Chemical Communications. 2018. V.54. N18. P.2236-2239. DOI: 10.1039/c8cc00245b WOS Scopus OpenAlex
Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction
Chemical Communications. 2018. V.54. N18. P.2236-2239. DOI: 10.1039/c8cc00245b WOS Scopus OpenAlex
Identifiers:
Web of science: | WOS:000426701900011 |
Scopus: | 2-s2.0-85042656161 |
OpenAlex: | W2785318549 |