Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction

Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2018, Volume: 54, Number: 18, Pages: 2236-2239 Pages count : 4 DOI: 10.1039/c8cc00245b

Authors

Smirnov Vladimir O. ¹ , Maslov Anton S. ^1,2 , Kokorekin Vladimir A. ^1,3 , Korlyukov Alexander A. ^4,5 , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow, Russian Federation
3	I. M. Sechenov First Moscow State Medical University, Trubetskaya st. 8-2, 119991 Moscow, Russian Federation
4	A. N. Nesmeyanov Institute of Organoelement Compounds, Vavilov str. 28, 119991 Moscow, Russian Federation
5	N. I. Pirogov Russian National Research Medical University, Ostrovitianov str., 1, 117997 Moscow, Russian Federation

A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C–B bond occurs via single electron reduction by a Cu(I) photocatalyst activated by visible light.

Smirnov V.O. , Maslov A.S. , Kokorekin V.A. , Korlyukov A.A. , Dilman A.D.
Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction
Chemical Communications. 2018. V.54. N18. P.2236-2239. DOI: 10.1039/c8cc00245b WOS Scopus OpenAlex

Web of science:	WOS:000426701900011
Scopus:	2-s2.0-85042656161
OpenAlex:	W2785318549

DB	Citing
OpenAlex	28
Scopus	27
Web of science	27