Synthesis, structures, and thermal properties of terpolymers of propylene oxide, carbon dioxide, and cyclohexene oxide

Synthesis, structures, and thermal properties of terpolymers of propylene oxide, carbon dioxide, and cyclohexene oxide Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2019, Volume: 68, Number: 11, Pages: 2119-2125 Pages count : 7 DOI: 10.1007/s11172-019-2676-z

Authors

Nysenko Z.N. ¹ , Said-Galiev E.E. ² , Buzin M.I. ² , Nikiforova G.G. ² , Il’in M.M. ² , Rusak V.V. ¹ , Sakharov A.M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Мoscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation

High molecular weight block terpolymers with different contents of polypropylene carbonate and cyclohexene carbonate units in the polymer chain were synthesized by the copolymerization of carbon dioxide, propylene oxide, and cyclohexene oxide. Zinc adipate was used as a catalyst. The terpolymerization products were characterized by 1H and 13C NMR spectroscopy, IR spectroscopy, GPC, DSC, and DMA methods. The influence of the reaction conditions on the composition, microstructure, and molecular-weight and thermal characteristics was studied.

Nysenko Z.N. , Said-Galiev E.E. , Buzin M.I. , Nikiforova G.G. , Il’in M.M. , Rusak V.V. , Sakharov A.M.
Synthesis, structures, and thermal properties of terpolymers of propylene oxide, carbon dioxide, and cyclohexene oxide
Russian Chemical Bulletin. 2019. V.68. N11. P.2119-2125. DOI: 10.1007/s11172-019-2676-z Scopus OpenAlex

≡ Scopus:	2-s2.0-85077677238
≡ OpenAlex:	W2996619625