Synthesis and Structure of N,N‐Dinitroamidoborane Complexes

Synthesis and Structure of N,N‐Dinitroamidoborane Complexes Full article

Journal

Chemistry-An Asian Journal
ISSN: 1861-471X , E-ISSN: 1861-4728

Output data

Year: 2017, Volume: 12, Number: 17, Pages: 2237-2244 Pages count : 8 DOI: 10.1002/asia.201700603

Authors

Shitov Oleg P. ¹ , Tartakovsky Vladimir A. ¹ , Golovanov Ivan S. ¹ , Sukhorukov Alexey Yu. ^2,1 , Ioffe Sema L. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry (ZIOC), Russian Science Academy, Leninsky prospect, 47, 1119991 Moscow, Russia
2	Dmitry Mendeleev University of Chemical Technology of Russia, Miusskaya sq. 9, 125047 Moscow, Russia

A general approach to the synthesis of borohydride complexes containing one or two dinitroamide fragments has been suggested. Based on a smooth substitution of halide in haloborane or dibromoborane complexes with N,N-dinitroamide salts, this method provides various N,N-dinitroamidoboranes complexes in good yields and in analytically pure form. By means of spectroscopic and computational methods, it was demonstrated that dinitroamidoborane complexes could form as both B,N- and B,O-isomers, which did not interconvert at ambient temperature.

Shitov O.P. , Tartakovsky V.A. , Golovanov I.S. , Sukhorukov A.Y. , Ioffe S.L.
Synthesis and Structure of N,N‐Dinitroamidoborane Complexes
Chemistry-An Asian Journal. 2017. V.12. N17. P.2237-2244. DOI: 10.1002/asia.201700603 WOS Scopus OpenAlex

Web of science:	WOS:000409257600016
Scopus:	2-s2.0-85028767047
OpenAlex:	W2682281245

DB	Citing
OpenAlex	10
Scopus	8
Web of science	8