Vinylation of Iododifluoromethylated Alcohols via a Light-Promoted Intramolecular Atom-Transfer Reaction Full article
| Journal |
Synthesis
ISSN: 1437-210X , E-ISSN: 0039-7881 |
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| Output data | Year: 2017, Volume: 49, Number: 18, Pages: 4124-4132 Pages count : 9 DOI: 10.1055/s-0036-1590855 | ||
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Abstract:
A method for the synthesis of gem-difluorohomoallylic alcohols by the substitution of iodine in the iododifluoromethyl group by a vinyl fragment is described. The reaction proceeds via an intramolecular iodine atom transfer followed by β-elimination. The reaction is performed in the presence of an iridium photocatalyst, fac-Ir(ppy)3, and triphenylphosphine under irradiation with light-emitting diodes.
Cite:
Panferova L.I.
, Struchkova M.I.
, Dilman A.D.
Vinylation of Iododifluoromethylated Alcohols via a Light-Promoted Intramolecular Atom-Transfer Reaction
Synthesis. 2017. V.49. N18. P.4124-4132. DOI: 10.1055/s-0036-1590855 WOS Scopus OpenAlex
Vinylation of Iododifluoromethylated Alcohols via a Light-Promoted Intramolecular Atom-Transfer Reaction
Synthesis. 2017. V.49. N18. P.4124-4132. DOI: 10.1055/s-0036-1590855 WOS Scopus OpenAlex
Identifiers:
| Web of science: | WOS:000409314200003 |
| Scopus: | 2-s2.0-85028557860 |
| OpenAlex: | W2744975782 |