Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides

Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2019, Volume: 29, Number: 1, Pages: 55-56 Pages count : 2 DOI: 10.1016/j.mencom.2019.01.017

Authors

Bityukov Oleg V. ^1,2 , Vil’ Vera A. ^3,2,1 , Lukashin Nikita V. ^3,1 , Cherednichenko Aleksandr G. ⁴ , Nikishin Gennady I. ¹ , Terent’ev Alexander O. ^3,2,1

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	All-Russian Research Institute for Phytopathology, 143050 B. Vyazyomy, Moscow Region, Russian Federation
3	D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
4	Peoples Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation

Silica gel was found to mediate decarboxylation of tetracarbonyl compounds with a free carboxylic group prepared from β-dicarbonyl compounds and malonyl peroxides. Under solvent-free heterogeneous conditions silica gel effectively acts as a mediator of C–O coupling with further decarboxylation at 120 °C.

Bityukov O.V. , Vil’ V.A. , Lukashin N.V. , Cherednichenko A.G. , Nikishin G.I. , Terent’ev A.O.
Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides
Mendeleev Communications. 2019. V.29. N1. P.55-56. DOI: 10.1016/j.mencom.2019.01.017 WOS Scopus OpenAlex

≡ Web of science:	WOS:000460711400017
≡ Scopus:	2-s2.0-85061555223
≡ OpenAlex:	W2913247623