1,2,5‐Oxadiazole‐Based High‐Energy‐Density Materials: Synthesis and Performance

1,2,5‐Oxadiazole‐Based High‐Energy‐Density Materials: Synthesis and Performance Review

Journal

ChemPlusChem
ISSN: 1212-6950 , E-ISSN: 0010-0765

Output data

Year: 2020, Volume: 85, Number: 1, Article number : e1900542, Pages count : 30 DOI: 10.1002/cplu.201900542

Authors

Fershtat Leonid L. ¹ , Makhova Nina N. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Leninsky Prospect, 47 Moscow, Russia

This Review covers the synthesis and performance of the most promising 1,2,5-oxadiazole-based high-energy density materials (HEDMs). These materials comprise a 1,2,5-oxadiazole subunit as a key structural motif linked to various acyclic explosophoric groups or to nitrogen-rich and nitrogen-oxygen azoles: 1,2,4-triazole, tetrazole, 1,2,4- and 1,3,4-oxadiazoles. Energetic alliances of two and more 1,2,5-oxadiazole rings linked directly or through heteroatom spacers are also presented. Particular attention is devoted to the installation of different explosophores: nitro, nitramino, azo, azoxy, dinitromethyl, trinitroethyl moieties and their combination. Promising environmentally benign energetic materials with high detonation velocity and pressure, and outstanding insensitivity are summarized. Overall, the presented materials may be considered as next-generation high-performance energetic materials that are superior to commonly used traditional explosives (TNT, PETN, RDX, HMX).

Fershtat L.L. , Makhova N.N.
1,2,5‐Oxadiazole‐Based High‐Energy‐Density Materials: Synthesis and Performance
ChemPlusChem. 2020. V.85. N1. e1900542 :1-30. DOI: 10.1002/cplu.201900542 OpenAlex

OpenAlex:

W2981184286

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