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An Energetic (Nitro‐NNO‐azoxy)triazolo‐1,2,4‐triazine Full article

Journal European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690
Output data Year: 2019, Volume: 2019, Number: 26, Pages: 4189-4195 Pages count : 7 DOI: 10.1002/ejoc.201900314
Authors Anikin Oleg V. 1 , Leonov Nikita E. 2,1 , Klenov Michael S. 1 , Churakov Aleksandr M. 1 , Voronin Alexey A. 1 , Muravyev Nikita V. 3 , Strelenko Yurii A. 1 , Fedyanin Ivan V. 4,5 , Tartakovsky Vladimir A. 1
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences,47 Leninsky prosp., 119991, Moscow, Russian Federation
2 Dmitry Mendeleev University of Chemical Technology of Russia, 9 Miusskaya sq., 125047, Moscow, Russian Federation
3 Semenov Institute of Chemical Physics, Russian Academy of Sciences4 Kosygina Street, Building 1, 119991, Moscow, Russian Federation
4 A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Russian Federation
5 Plekhanov Russian University of Economics, Stremyanny per. 36, Moscow,117997, Russian Federation

Abstract: 7-Nitro-3-(nitro-NNO-azoxy)[1,2,4]triazolo[5,1-c][1,2,4]-triazin-4-amine (4) is the first high-melting compound bearing adjacent nitro-NNO-azoxy and amino groups. It was synthesized by nitration of 7-nitro-3-(tert-butyl-NNO-azoxy)[1,2,4]triazolo[5,1-c][1,2,4]triazin-4-amine (3) with NO2BF4. Compound 4 is a rather thermally stable (decomposition onset temperature 154 °C), highly energetic (calculated heat of formation 580 kcal·kg–1), and highly dense (1.875 g cm–3) material with a CO-level oxygen balance.
Cite: Anikin O.V. , Leonov N.E. , Klenov M.S. , Churakov A.M. , Voronin A.A. , Muravyev N.V. , Strelenko Y.A. , Fedyanin I.V. , Tartakovsky V.A.
An Energetic (Nitro‐NNO‐azoxy)triazolo‐1,2,4‐triazine
European Journal of Organic Chemistry. 2019. V.2019. N26. P.4189-4195. DOI: 10.1002/ejoc.201900314 WOS Scopus OpenAlex
Identifiers:
≡ Web of science: WOS:000475679400012
≡ Scopus: 2-s2.0-85067584419
≡ OpenAlex: W2948008737
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