Pyrazolyltetrazoles—a High-Enthalpy Backbone for Designing High-Energy Compounds: An Experimental Study of the Enthalpy of Formation

Pyrazolyltetrazoles—a High-Enthalpy Backbone for Designing High-Energy Compounds: An Experimental Study of the Enthalpy of Formation Full article

Journal

Doklady Physical Chemistry
ISSN: 1608-3121 , E-ISSN: 0012-5016

Output data

Year: 2018, Volume: 478, Number: 1, Pages: 15-18 Pages count : 4 DOI: 10.1134/s0012501618010049

Authors

Kazakov A.I. ¹ , Kurochkina L.S. ¹ , Nabatova A.V. ¹ , Lempert D.B. ¹ , Dalinger I.L. ² , Kormanov A.V. ² , Serushkina O.V. ² , Sheremetev A.B. ²

Affiliations

1	Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia
2	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

The standard enthalpies of combustion and formation of isomeric nitropyrazolyltetrazoles have been measured by combustion calorimetry. Positional isomerism has been shown to have a significant effect on thermochemical characteristics. The contributions of some explosophore groups and moieties to the total heat content of the molecules have been determined. These contributions can be used to correctly calculate the enthalpy of formation of both known and hypothetical energy-intensive compounds.

Kazakov A.I. , Kurochkina L.S. , Nabatova A.V. , Lempert D.B. , Dalinger I.L. , Kormanov A.V. , Serushkina O.V. , Sheremetev A.B.
Pyrazolyltetrazoles—a High-Enthalpy Backbone for Designing High-Energy Compounds: An Experimental Study of the Enthalpy of Formation
Doklady Physical Chemistry. 2018. V.478. N1. P.15-18. DOI: 10.1134/s0012501618010049 WOS Scopus OpenAlex

≡ Web of science:	WOS:000426081600004
≡ Scopus:	2-s2.0-85042564318
≡ OpenAlex:	W2793256332