A New Simple Procedure for the Synthesis of Heptamethyl Cyclohepta-1,3,5-triene-1,2,3,4,5,6,7-heptacarboxylate

A New Simple Procedure for the Synthesis of Heptamethyl Cyclohepta-1,3,5-triene-1,2,3,4,5,6,7-heptacarboxylate Full article

Journal

Synlett
ISSN: 0936-5214 , E-ISSN: 1437-2096

Output data

Year: 2018, Volume: 29, Number: 09, Pages: 1157-1160 Pages count : 4 DOI: 10.1055/s-0036-1591962

Authors

Belyy Alexander Yu. ¹ , Platonov Dmitry N. ¹ , Salikov Rinat F. ¹ , Levina Anastasiya A. ² , Tomilov Yury V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2	Higher Chemical College of the Russian Academy of Sciences

A new and simple procedure for the synthesis of heptamethyl cyclohepta-1,3,5-triene-1,2,3,4,5,6,7-heptacarboxylate in a 51% yield is presented. An optimization of the reaction conditions was performed, and a convenient protocol for the isolation of the reaction product was developed. The structure of the key electrophilic intermediate was determined by means of NMR spectroscopy, and a plausible reaction mechanism is proposed.

Belyy A.Y. , Platonov D.N. , Salikov R.F. , Levina A.A. , Tomilov Y.V.
A New Simple Procedure for the Synthesis of Heptamethyl Cyclohepta-1,3,5-triene-1,2,3,4,5,6,7-heptacarboxylate
Synlett. 2018. V.29. N09. P.1157-1160. DOI: 10.1055/s-0036-1591962 WOS Scopus OpenAlex

≡ Web of science:	WOS:000432738600005
≡ Scopus:	2-s2.0-85044345082
≡ OpenAlex:	W2793973640