Are N-phthaloyl and O-allyl protective groups orthogonal? | Sciact

Are N-phthaloyl and O-allyl protective groups orthogonal? Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2019, Том: 68, Номер: 9, Страницы: 1791-1794 Страниц : 4 DOI: 10.1007/s11172-019-2626-9

Авторы

Orlova A.V. ¹ , Volodin D.A. ¹ , Zinin A.I. ¹ , Kononov L.O. ^2,1

Организации

1	N. D. Zelinskiy Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninskiy prosp., 119991 Moscow, Russian Federation
2	Moscow Physico-Technical Institute (National Research University), 9 Institutskiy per., 141701 Dolgoprudnyi, Moscow Region, Russian Federation

Using allyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranoside as a model substrate, it was shown that the degree of orthogonality of N-phthaloyl and O-allyl protective groups under the conditions of hydrazinolysis of the phthalimide group depends on the amount of atmospheric oxygen in the reaction mixture during the reaction and during the work-up procedure.

Orlova A.V. , Volodin D.A. , Zinin A.I. , Kononov L.O.
Are N-phthaloyl and O-allyl protective groups orthogonal?
Russian Chemical Bulletin. 2019. V.68. N9. P.1791-1794. DOI: 10.1007/s11172-019-2626-9 WOS Scopus OpenAlex

Web of science:	WOS:000489761800022
Scopus:	2-s2.0-85074517724
OpenAlex:	W2977974412

БД	Цитирований
OpenAlex	Нет цитирований
Scopus	Нет цитирований