Polynitromethyl derivatives of furazano[3,4-e]di([1,2,4]triazolo)-[4,3-a:3′,4′-c]pyrazine as components of solid composite propellants

Polynitromethyl derivatives of furazano[3,4-e]di([1,2,4]triazolo)-[4,3-a:3′,4′-c]pyrazine as components of solid composite propellants Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2018, Volume: 67, Number: 11, Pages: 2065-2072 Pages count : 8 DOI: 10.1007/s11172-018-2330-1

Authors

Lempert D.B. ¹ , Sheremetev A.B. ²

Affiliations

1	Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

The energetic potential of solid composite propellants (SCP) with furazano[3,4-e]di([1,2,4]- triazolo)[4,3-a:3′,4′-c]pyrazine including trinitromethyl (C(NO2)3), fluorodinitromethyl (CF(NO2)2), and (difluoroamino)dinitromethyl (C(NF2)(NO2)2) groups was estimated based on thermochemical calculations. It was shown that C(NO2)3 and C(NF2)(NO2)2 derivatives can constitute the basis of metal-free compositions of SCP with a specific impulse from 251 to 263 s, i.e., comparable or superior in efficiency to HMX-based propellants.

Lempert D.B. , Sheremetev A.B.
Polynitromethyl derivatives of furazano[3,4-e]di([1,2,4]triazolo)-[4,3-a:3′,4′-c]pyrazine as components of solid composite propellants
Russian Chemical Bulletin. 2018. V.67. N11. P.2065-2072. DOI: 10.1007/s11172-018-2330-1 WOS Scopus OpenAlex

≡ Web of science:	WOS:000454510700017
≡ Scopus:	2-s2.0-85059340905
≡ OpenAlex:	W2907153771