3,3′-(Diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide]

3,3′-(Diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide] Full article

Journal

Molbank
ISSN: 1422-8599

Output data

Year: 2018, Volume: 2018, Number: 3, Article number : M1003, Pages count : DOI: 10.3390/m1003

Authors

Larin Alexander ¹ , Ovchinnikov Igor ¹ , Fershtat Leonid ¹ , Makhova Nina ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, Moscow 119991, Russia

The nitramino derivatives of furoxans are of specific interest as precursors for the preparation of high energy salts with nitrogen-rich cations. In this communication, the 3,3′-(diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide] was prepared via nitration of available 4,4′-diamino-3,3′-diazenofuroxan; the best yield of the target compound was achieved under the action of nitrating system HNO3/(CF3CO)2O in molar ratio 15:3 in CCl4 at −5 °C. The structure of 3,3′-(diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide] was confirmed by means of 1H, 13C,14N-NMR, IR spectroscopy and high resolution mass spectra (HRMS).

Larin A. , Ovchinnikov I. , Fershtat L. , Makhova N.
3,3′-(Diazene-1,2-diyl)bis[4-(nitroamino)-1,2,5-oxadiazole 2-oxide]
Molbank. 2018. V.2018. N3. M1003 . DOI: 10.3390/m1003 WOS Scopus OpenAlex

Web of science:	WOS:000445214100003
Scopus:	2-s2.0-85050919764
OpenAlex:	W2835419581

DB	Citing
OpenAlex	8
Web of science	5
Scopus	2