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Efficient hydrogenation of benzaldoximes and Schiff bases on ceramic high-porosity palladium catalysts Научная публикация

Журнал Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285
Вых. Данные Год: 2018, Том: 67, Номер: 8, Страницы: 1394-1400 Страниц : 7 DOI: 10.1007/s11172-018-2230-4
Авторы Ignatov A.V. 1 , Varakutin A.E. 2 , Solov’eva I.N. 2 , Karmanova I.B. 1 , Kozlov I.A. 3 , Semenova M.N. 4 , Semenov V.V. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2 D. I. Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
3 NOATEQ Ltd., Building 10, Moscow, Russian Federation
4 N. K. Koltzov Institute of Developmental Biology, Russian Academy of Sciences, Moscow, Russian Federation

Реферат: An efficient catalytic method for the synthesis of benzyl- and dibenzylamines by hydrogenating oximes and Schiffbases was developed on palladium supported high-porosity foamed ceramic block catalyst. The multiple regeneration ability of the foamed ceramic block catalyst can significantly decrease the Pd consumption as compared to the use of the conventional 10%Pd/C catalyst. Owing to a high hardness of the foamed ceramic catalyst, the reaction mixture can rapidly be removed from the reactor without using filtering devices. The structures produced by the reaction are fragments of biologically active and natural molecules. Antiproliferative properties of dibenzylamines revealed on the sea urchin embryo model suggest that these compounds can be considered as promising agents for the design of new anticancer drugs.
Библиографическая ссылка: Ignatov A.V. , Varakutin A.E. , Solov’eva I.N. , Karmanova I.B. , Kozlov I.A. , Semenova M.N. , Semenov V.V.
Efficient hydrogenation of benzaldoximes and Schiff bases on ceramic high-porosity palladium catalysts
Russian Chemical Bulletin. 2018. V.67. N8. P.1394-1400. DOI: 10.1007/s11172-018-2230-4 WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: WOS:000448221900011
Scopus: 2-s2.0-85055338256
OpenAlex: W2898399325
Цитирование в БД:
БД Цитирований
OpenAlex 8
Scopus 8
Web of science 6
Альметрики: