Electrochemical behavior of phthaloyl peroxide in aqueous media

Electrochemical behavior of phthaloyl peroxide in aqueous media Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2017, Volume: 66, Number: 11, Pages: 2044-2047 Pages count : 4 DOI: 10.1007/s11172-017-1979-1

Authors

Vedenyapina M.D. ^1,2 , Vil V.A. ¹ , Terent’ev A.O. ¹ , Vedenyapin A.A. ^2,1

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	Moscow Technological Institute, 38a Leninsky prosp., 119334, Moscow, Russian Federation

The electrochemical behavior of phthaloyl peroxide C8H4O4 on an Au disk electrode in a 0.05 M aqueous solution of Na2SO4 was studied by cyclic voltammetry (CVA). It demonstrated a high activity in cathodic reduction with the formation of an irreversible peak on the CVA curve at E =–0.81 V. Additionally, during the anodic oxidation of C8H4O4, the surface of the Au electrode became passivated by compounds which prevented its oxidation during the registration of repeated cycles. Apparently, these compounds are surface complexes of phthaloyl peroxide with a gold cation.

Vedenyapina M.D. , Vil V.A. , Terent’ev A.O. , Vedenyapin A.A.
Electrochemical behavior of phthaloyl peroxide in aqueous media
Russian Chemical Bulletin. 2017. V.66. N11. P.2044-2047. DOI: 10.1007/s11172-017-1979-1 WOS Scopus OpenAlex

Web of science:	WOS:000427628900009
Scopus:	2-s2.0-85043980970
OpenAlex:	W2794293210

DB	Citing
OpenAlex	6
Scopus	5
Web of science	5