Synthesis of 3,5-dimethyl-1-boraadamantane and its transformation into 3,5-dimethyl-1-azaadamantane

Synthesis of 3,5-dimethyl-1-boraadamantane and its transformation into 3,5-dimethyl-1-azaadamantane Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2018, Volume: 28, Number: 4, Pages: 366-368 Pages count : 3 DOI: 10.1016/j.mencom.2018.07.008

Authors

Gurskii Mikhail E. ¹ , Kolomnikova Galina D. ² , Baranin Sergey V. ¹ , Bubnov Yurii N. ^1,2

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The first synthesis of 3,5-dimethyl-1-boraadamantane from its easily available tetrahydrofuran adduct comprised sequential treatment with BuLi, AcCl, (Cy2BH)2 and heating. The compound was converted into its electronic ‘antagonist’, namely, 3,5-dimethyl-1-azaadamantane.

Gurskii M.E. , Kolomnikova G.D. , Baranin S.V. , Bubnov Y.N.
Synthesis of 3,5-dimethyl-1-boraadamantane and its transformation into 3,5-dimethyl-1-azaadamantane
Mendeleev Communications. 2018. V.28. N4. P.366-368. DOI: 10.1016/j.mencom.2018.07.008 WOS Scopus OpenAlex

≡ Web of science:	WOS:000442709700008
≡ Scopus:	2-s2.0-85051050620
≡ OpenAlex:	W2887215390