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Synthesis and Reactivity of 3H-1,2-dithiole-3-thiones Review

Journal Molecules
ISSN: 1420-3049
Output data Year: 2021, Volume: 26, Number: 12, Article number : 3595, Pages count : DOI: 10.3390/molecules26123595
Authors Rakitin Oleg A 1,2
Affiliations
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect, 119991 Moscow, Russia
2 Nanotechnology Education and Research Center, South Ural State University, 454080 Chelyabinsk, Russia

Abstract: 3H-1,2-Dithiole-3-thiones are among the best studied classes of polysulfur-containing heterocycles due to the almost explosive recent interest in these compounds as sources of hydrogen sulfide as an endogenously produced gaseous signaling molecule. This review covers the recent developments in the synthesis of these heterocycles, including both well-known procedures and important novel transformations for building the 1,2-dithiole-3-thione ring. Diverse ring transformations of 3H-1,2-dithiole-3-thiones into various heterocyclic systems through 1,3-dipolar cycloaddition, replacement of one or two sulfur atoms to form carbon- and carbon-nitrogen containing moieties, and other unexpected reactions are considered.
Cite: Rakitin O.A.
Synthesis and Reactivity of 3H-1,2-dithiole-3-thiones
Molecules. 2021. V.26. N12. 3595 . DOI: 10.3390/molecules26123595 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000666709600001
Scopus: 2-s2.0-85108348821
OpenAlex: W3169398341
Citing:
DB Citing
OpenAlex 22
Scopus 21
Web of science 19
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