Реферат: The structure and catalytic characteristics of a series of Pd–Cu/α-Al2O3 catalysts with Pd: Cu ratio varied from Pd1–Cu0.5 to Pd1–Cu4 were studied. The use of α-Al2O3 with a small surface area (Ssp = 8 m2/g) as a support made it possible to minimize the effect of diffusion on the catalytic characteristics and to study the structure of Pd–Cu nanoparticles by X-ray diffraction (XRD) analysis. The XRD analysis and transmission electron microscopy (TEM) data indicated the formation of uniform bimetallic Pd–Cu nanoparticles (d = 20–60 nm), whose composition corresponded to a ratio between the metals in the catalyst, and also the absence of monometallic Pd0 and Cu0 nanoparticles. The study of catalytic properties in the liquid-phase hydrogenation of diphenylacetylene (DPA) showed that the activity of the catalysts rapidly decreased with the Cu content increase; however, in this case, the yield of a desired alkene compound significantly increased. The selectivity of alkene formation on the catalysts with the ratios Pd: Cu = 1: 3 and 1: 4 was superior to the commercial Lindlar catalyst.

Библиографическая ссылка: Markov P.V. , Bragina G.O. , Baeva G.N. , Rassolov A.V. , Mashkovsky I.S. , Stakheev A.Y.
Highly Selective Pd–Cu/α-Al2O3 Catalysts for Liquid-Phase Hydrogenation: The Influence of the Pd: Cu Ratio on the Structure and Catalytic Characteristics
Kinetics and Catalysis. 2018. V.59. N5. P.601-609. DOI: 10.1134/s0023158418050105 WOS Scopus OpenAlex

Идентификаторы БД:

Web of science:	WOS:000445762600009
Scopus:	2-s2.0-85053910807
OpenAlex:	W2893135268

Цитирование в БД:

БД	Цитирований
OpenAlex	7
Scopus	6
Web of science	6

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