Dearomatization of 3,5-dinitropyridines – an atom-efficient approach to fused 3-nitropyrrolidines

Dearomatization of 3,5-dinitropyridines – an atom-efficient approach to fused 3-nitropyrrolidines Full article

Journal

Arkivoc
ISSN: 1551-7012 , E-ISSN: 1551-7004

Output data

Year: 2017, Number: 3, Pages: 181-190 Pages count : 10 DOI: 10.24820/ark.5550190.p010.185

Authors

Bastrakov Maxim A. ¹ , Kucherova Anna Yu. ¹ , Fedorenko Alexey K. ¹ , Starosotnikov Alexey M. ¹ , Fedyanin Ivan V. ² , Dalinger Igor L. ¹ , Shevelev Svyatoslav A. ¹

Affiliations

1	Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky prosp. 47, Moscow 119 991, Russian Federation
2	A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilova st. 28, Moscow, 119 991, Russian Federation

An efficient and convenient one-step method for the synthesis of decahydrodipyrrolo[3,4-b:3',4'-d]pyridine derivatives was developed on the basis of 1,3-dipolar cycloaddition of unstabilized N-methyl azomethine ylide with 2-substituted 3,5-dinitropyridines. This novel heterocyclic system contains two 3-nitropyrrolidine fragments fused to a partially saturated pyridine ring. Such types of compound, as follows from the literature, can be considered as potential nitric oxide donors.

Bastrakov M.A. , Kucherova A.Y. , Fedorenko A.K. , Starosotnikov A.M. , Fedyanin I.V. , Dalinger I.L. , Shevelev S.A.
Dearomatization of 3,5-dinitropyridines – an atom-efficient approach to fused 3-nitropyrrolidines
Arkivoc. 2017. N3. P.181-190. DOI: 10.24820/ark.5550190.p010.185 Scopus OpenAlex

Scopus:	2-s2.0-85082959736
OpenAlex:	W2775558100

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OpenAlex	15
Scopus	3