Synthesis of N-β-haloethyl derivatives of bis(oxytriazene oxides) bearing the NCH2O fragment

Synthesis of N-β-haloethyl derivatives of bis(oxytriazene oxides) bearing the NCH2O fragment Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2018, Volume: 67, Number: 1, Pages: 85-94 Pages count : 10 DOI: 10.1007/s11172-018-2041-7

Authors

Gordeev P.B. ¹ , Smirnov G.A. ¹ , Nikitin S.V. ¹ , Pokhvisneva G.V. ¹ , Ternikova T.V. ¹ , Luk’yanov O.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Synthetic procedures towards 3-monosubstituted functional derivatives of 1-alkoxy-1-triazene 2-oxides were elaborated. Alkylation of the synthesized compounds with chloromethoxy derivatives of 3,3-bis(2-haloethyl)-1-hydroxy-1-triazene 2-oxides gave (2-chloro/ bromoethyl) derivatives of 1,2,3,6,7,8-hexaaza-5-oxa-3-alkoxyocta-1,6-diene 2,7-dioxides. 2-Iodoethyl-1,2,3,6,7,8-hexaaza-5-oxa-3-alkoxyocta-1,6-diene 2,7-dioxides were first synthesized by the reaction of the corresponding bromoethyl derivatives with NaI.

Gordeev P.B. , Smirnov G.A. , Nikitin S.V. , Pokhvisneva G.V. , Ternikova T.V. , Luk’yanov O.A.
Synthesis of N-β-haloethyl derivatives of bis(oxytriazene oxides) bearing the NCH2O fragment
Russian Chemical Bulletin. 2018. V.67. N1. P.85-94. DOI: 10.1007/s11172-018-2041-7 WOS Scopus OpenAlex

≡ Web of science:	WOS:000430480200012
≡ Scopus:	2-s2.0-85045834600
≡ OpenAlex:	W2800966768