New data on heteroarene thiocyanation by anodic oxidation of NH4SCN. The processes of electroinduced nucleophilic aromatic substitution of hydrogen

New data on heteroarene thiocyanation by anodic oxidation of NH4SCN. The processes of electroinduced nucleophilic aromatic substitution of hydrogen Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 2014, Volume: 55, Number: 31, Pages: 4306-4309 Pages count : 4 DOI: 10.1016/j.tetlet.2014.06.028

Authors

Kokorekin Vladimir A. ¹ , Sigacheva Vera L. ¹ , Petrosyan Vladimir A. ¹

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991,Moscow, Russian Federation

Potentiostatic (galvanostatic) electrolysis of NH4SCN in an undivided cell under mild conditions (25 °C, Pt anode, MeCN) was employed to perform the anodic thiocyanation of nitrogen-containing heterocycles with yields up to 95%. The regularities of the process are discussed, which show that it can be considered as electroinduced nucleophilic aromatic substitution of hydrogen.

Kokorekin V.A. , Sigacheva V.L. , Petrosyan V.A.
New data on heteroarene thiocyanation by anodic oxidation of NH4SCN. The processes of electroinduced nucleophilic aromatic substitution of hydrogen
Tetrahedron Letters. 2014. V.55. N31. P.4306-4309. DOI: 10.1016/j.tetlet.2014.06.028 WOS Scopus OpenAlex

≡ Web of science:	WOS:000339695700005
≡ Scopus:	2-s2.0-84904176098
≡ OpenAlex:	W2952157391