Reductive silylation of gem-difluorinated phosphonium salts

Reductive silylation of gem-difluorinated phosphonium salts Full article

Journal

Journal of Fluorine Chemistry
ISSN: 1873-3328 , E-ISSN: 0022-1139

Output data

Year: 2018, Volume: 205, Pages: 58-61 Pages count : 4 DOI: 10.1016/j.jfluchem.2017.11.009

Authors

Tsymbal Artem V. ^1,2 , Levin Vitalij V. ¹ , Struchkova Marina I. ¹ , Kokorekin Vladimir A. ^1,3 , Korlyukov Alexander A. ^4,5 , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991, Moscow, Leninsky prosp. 47, Russian Federation
2	M. V. Lomonosov Moscow State University, Department of Chemistry, 119991, Moscow, Leninskie Gory 1-3, Russian Federation
3	I. M. Sechenov First Moscow State Medical University; 119991 Moscow Trubetskaya st. 8-2 Russian Federation
4	A. N. Nesmeyanov Institute of Organoelement Compounds, 119991, Moscow, Vavilov str. 28, Russian Federation
5	N. I. Pirogov Russian National Research Medical University Ostrovitianov str., 1 117997 Moscow Russian Federation

gem-Difluorinated phosphonium salts, generated from aldehydes and difluorinated phosphobetaine reagent, were converted into corresponding silicon reagents. The reductive silylation of carbon-phosphorus bond is carried out using a combination of magnesium and chlorotrimethylsilane in dimethylformamide. For a model difluoroined phosphonium salt, X-ray structure and reduction potential are provided.

Tsymbal A.V. , Levin V.V. , Struchkova M.I. , Kokorekin V.A. , Korlyukov A.A. , Dilman A.D.
Reductive silylation of gem-difluorinated phosphonium salts
Journal of Fluorine Chemistry. 2018. V.205. P.58-61. DOI: 10.1016/j.jfluchem.2017.11.009 WOS Scopus OpenAlex

Web of science:	WOS:000424180500010
Scopus:	2-s2.0-85038847883
OpenAlex:	W2768281918

DB	Citing
OpenAlex	5
Scopus	6