Pinacol rearrangement of cyclopent-3-en-1,2-diols: Cyclopentenone formation and interrupting reaction

Pinacol rearrangement of cyclopent-3-en-1,2-diols: Cyclopentenone formation and interrupting reaction Full article

Journal

Tetrahedron Letters
ISSN: 0040-4039 , E-ISSN: 1873-3581

Output data

Year: 2018, Volume: 59, Number: 3, Pages: 243-246 Pages count : 4 DOI: 10.1016/j.tetlet.2017.12.016

Authors

Shirinian Valerii Z. ¹ , Lvov Andrey G. ¹ , Lonshakov Dmitry V. ¹ , Yadykov Anton V. ^1,2 , Kachala Vadim V. ¹ , Krayushkin Mikhail M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, RAS, Moscow 119991, Russia
2	Higher Chemical College, D.I. Mendeleev University of Chemical Technology of Russia, Moscow 125047, Russia

Cyclopentenyl carbocations formed as a result of the protonation of 3,4-substituted cyclopent-3-en-1,2-diols can give either cyclopent-2-en-1-one derivatives via pinacol rearrangement or interrupted reaction products similar to the Nazarov intermediate.

Shirinian V.Z. , Lvov A.G. , Lonshakov D.V. , Yadykov A.V. , Kachala V.V. , Krayushkin M.M.
Pinacol rearrangement of cyclopent-3-en-1,2-diols: Cyclopentenone formation and interrupting reaction
Tetrahedron Letters. 2018. V.59. N3. P.243-246. DOI: 10.1016/j.tetlet.2017.12.016 WOS Scopus OpenAlex

Web of science:	WOS:000424308900011
Scopus:	2-s2.0-85037602166
OpenAlex:	W2772971581

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OpenAlex	8
Scopus	6
Web of science	5