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Ring Opening of Naphthene Hydrocarbons under Conditions of Thermal and Microwave Heating Full article

Journal Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Output data Year: 2018, Volume: 92, Number: 12, Pages: 2408-2411 Pages count : 4 DOI: 10.1134/s0036024418120130
Authors Finashina E.D. 1 , Tarasov A.L. 1
Affiliations
1 Zelinsky Institute of Organic Chemistry, Moscow, Russia

Abstract: A comparative study of the activity and selectivity of monometallic Ir-containing catalysts in ring opening reactions under conditions of thermal and microwave heating is performed using the example of cyclohexane. The hydrogenolysis of cyclohexane is shown to be possible with microwave activation. It is found that upon microwave heating, iridium-containing catalysts supported on titanium oxide and activated carbon allow 60% selectivity to be reached with respect to ring opening products at 30% conversion of the initial cyclohexane.
Cite: Finashina E.D. , Tarasov A.L.
Ring Opening of Naphthene Hydrocarbons under Conditions of Thermal and Microwave Heating
Russian Journal of Physical Chemistry A. 2018. V.92. N12. P.2408-2411. DOI: 10.1134/s0036024418120130 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000453064000012
Scopus: 2-s2.0-85058557556
OpenAlex: W2904727171
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