The Ozone and Hydroperoxide Teamwork: Synthesis of Unsymmetrical Geminal Bisperoxides from Alkenes

The Ozone and Hydroperoxide Teamwork: Synthesis of Unsymmetrical Geminal Bisperoxides from Alkenes Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2023, Volume: 25, Number: 25, Pages: 4672-4676 Pages count : 5 DOI: 10.1021/acs.orglett.3c01477

Authors

Fomenkov Dmitri I. ¹ , Budekhin Roman A. ¹ , Vil' Vera A. ¹ , Terent'ev Alexander O. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., Moscow, 119991, Russian Federation

Alkene ozonolysis is mostly known as a textbook reaction, resulting in carbonyl compounds. The combination of ozone and hydroperoxide was found to lead to the construction of more oxygen-rich compounds, unsymmetrical geminal bisperoxides, avoiding as well further oxidation with ozone, hydroperoxide, and oxygen as peroxide rearrangements. The discovered three-component synthesis provided alkylperoxy hydroperoxides in 41–63% yield from alkenes.

Fomenkov D.I. , Budekhin R.A. , Vil' V.A. , Terent'ev A.O.
The Ozone and Hydroperoxide Teamwork: Synthesis of Unsymmetrical Geminal Bisperoxides from Alkenes
Organic Letters. 2023. V.25. N25. P.4672-4676. DOI: 10.1021/acs.orglett.3c01477 WOS Scopus OpenAlex

Web of science:	WOS:001016694900001
Scopus:	2-s2.0-85164234432
OpenAlex:	W4381309661

DB	Citing
OpenAlex	4
Scopus	4
Web of science	5