Visible light-mediated difluoroalkylation of electron-deficient alkenes

Visible light-mediated difluoroalkylation of electron-deficient alkenes Full article

Journal

Beilstein Journal of Organic Chemistry
ISSN: 2195-951X , E-ISSN: 1860-5397

Output data

Year: 2018, Volume: 14, Pages: 1637-1641 Pages count : 5 DOI: 10.3762/bjoc.14.139

Authors

Supranovich Vyacheslav I. ¹ , Levin Vitalij V. ¹ , Struchkova Marina I. ¹ , Hu Jinbo ² , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation
2	Key Laboratory of Organofluorine Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Ling-Ling Road, Shanghai 200032, China

A method for the reductive difluoroalkylation of electron-deficient alkenes using 1,1-difluorinated iodides mediated by irradiation with blue light is described. The reaction involves radical addition of 1,1-difluorinated radicals at the double bond followed by hydrogen atom transfer from sodium cyanoborohydride.

Supranovich V.I. , Levin V.V. , Struchkova M.I. , Hu J. , Dilman A.D.
Visible light-mediated difluoroalkylation of electron-deficient alkenes
Beilstein Journal of Organic Chemistry. 2018. V.14. P.1637-1641. DOI: 10.3762/bjoc.14.139 WOS Scopus OpenAlex

Web of science:	WOS:000437409700001
Scopus:	2-s2.0-85049722838
OpenAlex:	W2810212855

DB	Citing
OpenAlex	14
Scopus	14