Arabinofuranose 1,2,5-orthobenzoate as a single precursor of linear α(1 → 5)-linked oligoarabinofuranosides

Arabinofuranose 1,2,5-orthobenzoate as a single precursor of linear α(1 → 5)-linked oligoarabinofuranosides Full article

Journal

Carbohydrate Research
ISSN: 1873-426X , E-ISSN: 0008-6215

Output data

Year: 2018, Volume: 456, Pages: 35-44 Pages count : 10 DOI: 10.1016/j.carres.2017.11.002

Authors

Panova Maria V. ^1,2 , Podvalnyy Nikita M. ¹ , Okun Eugene L. ¹ , Abronina Polina I. ¹ , Chizhov Alexander O. ¹ , Kononov Leonid O. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, Leninsky Prosp., 47, 119991 Moscow, Russian Federation
2	The Higher Chemical College of the Russian Academy of Sciences, Miusskaya Pl. 9, 125047 Moscow, Russian Federation

Selectively protected mono-, di- and trisaccharide thioglycoside building blocks with unprotected primary hydroxy group at the non-reducing end, available in only one step from 3-O-benzoyl β-d-arabinofuranose 1,2,5-orthobenzoate, were used in the synthesis of linear α(1 → 5)-linked oligoarabinofuranosides up to octasaccharide. The obtained oligosaccharides contain 4-(2-chloroethoxy)phenyl (CEP) or 4-(2-azidoethoxy)phenyl (AEP) pre-spacer aglycons that allow preparation of neoglycoconjugates.

Panova M.V. , Podvalnyy N.M. , Okun E.L. , Abronina P.I. , Chizhov A.O. , Kononov L.O.
Arabinofuranose 1,2,5-orthobenzoate as a single precursor of linear α(1 → 5)-linked oligoarabinofuranosides
Carbohydrate Research. 2018. V.456. P.35-44. DOI: 10.1016/j.carres.2017.11.002 WOS Scopus OpenAlex

Web of science:	WOS:000426003000007
Scopus:	2-s2.0-85038240990
OpenAlex:	W2775138463

DB	Citing
OpenAlex	19
Scopus	21
Web of science	20