Visible Light Promoted 2-Bromotetrafluoroethylation of Nitrones

Visible Light Promoted 2-Bromotetrafluoroethylation of Nitrones Full article

Journal

Advanced Synthesis & Catalysis
ISSN: 1615-4169 , E-ISSN: 1615-4150

Output data

Year: 2018, Volume: 360, Number: 19, Pages: 3788-3792 Pages count : 5 DOI: 10.1002/adsc.201800802

Authors

Dmitriev Igor A. ^1,2 , Supranovich Vyacheslav I. ¹ , Levin Vitalij V. ¹ , Struchkova Marina I. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation
2	Moscow State University, Department of Chemistry, 119991 Moscow, Leninskie Gory 1-3, Russian Federation

A reaction of nitrones with 1,2-dibromotetrafluoroethane affording bromodifluoroethyl-substituted hydroxylamines is described. The process is performed in the presence of a ruthenium photocatalyst and ascorbic acid as a stoichiometric reducing agent and is mediated by blue light irradiation. The fluroalkylation products can undergo chemoselective transformations involving either N−O or C−Br bonds furnishing various tetrafluorinated compounds.

Dmitriev I.A. , Supranovich V.I. , Levin V.V. , Struchkova M.I. , Dilman A.D.
Visible Light Promoted 2-Bromotetrafluoroethylation of Nitrones
Advanced Synthesis & Catalysis. 2018. V.360. N19. P.3788-3792. DOI: 10.1002/adsc.201800802 WOS Scopus OpenAlex

Web of science:	WOS:000446304600019
Scopus:	2-s2.0-85053231661
OpenAlex:	W2884465547

DB	Citing
OpenAlex	11
Scopus	11