Oxidative coupling of N-hydroxyphthalimide with toluene Научная публикация
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Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350 |
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| Вых. Данные | Год: 2014, Том: 84, Номер: 11, Страницы: 2084-2087 Страниц : 4 DOI: 10.1134/s1070363214110061 | ||
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Реферат:
Oxidative C-O-coupling of N-hydroxyphthalimide (NHPI) with toluene was studied. The reaction occurred in different organic solvents with a wide range of oxidants, such as (NH4)2Ce(NO3)6, PhI(OAc)2, KMnO4, Mn(OAc)3·2H2O, Pb(OAc)4, and Co(OAc)2/O2, to afford N-benzyloxyphthalimide in yield of 11–75%. Phthalimide-N-oxyl radicals, generated under the reaction conditions, could eliminate the hydrogen atom from the benzyl fragment of alkylarene at room temperature. Probably, formation of the product of the oxidative coupling occurred via recombination of benzyl and phthalimide-N-oxyl radicals.
Библиографическая ссылка:
Terent’ev A.O.
, Krylov I.B.
, Lipatnikov A.D.
Oxidative coupling of N-hydroxyphthalimide with toluene
Russian Journal of General Chemistry. 2014. V.84. N11. P.2084-2087. DOI: 10.1134/s1070363214110061 WOS Scopus OpenAlex
Oxidative coupling of N-hydroxyphthalimide with toluene
Russian Journal of General Chemistry. 2014. V.84. N11. P.2084-2087. DOI: 10.1134/s1070363214110061 WOS Scopus OpenAlex
Идентификаторы БД:
| ≡ Web of science: | WOS:000346494400006 |
| ≡ Scopus: | 2-s2.0-84918831738 |
| ≡ OpenAlex: | W2460265601 |