Ethane oxidative dehydrogenation to ethylene in a membrane reactor with asymmetric ceramic membranes

Ethane oxidative dehydrogenation to ethylene in a membrane reactor with asymmetric ceramic membranes Научная публикация

Журнал

Chemical Engineering and Processing
ISSN: 1873-3204 , E-ISSN: 0255-2701

Вых. Данные

Год: 2018, Том: 126, Страницы: 150-155 Страниц : 6 DOI: 10.1016/j.cep.2018.02.011

Авторы

Ermilova Margarita ¹ , Kucherov Alexey ² , Orekhova Natalia ¹ , Finashina Elena ² , Kustov Leonid ² , Yaroslavtsev Andrey ^1,3

Организации

1	Topchiev Institute of Petrochemical Synthesis, RAS, Leninsky Pr. 29, Moscow, 119991, Russia
2	Zelinsky Institute of Organic Chemistry, RAS, Leninskii Pr. 47, Moscow, 119991, Russia
3	Kurnakov Institute of General and Inorganic Chemistry, RAS, Leninsky Pr. 31, Moscow, 119991, Russia

The process of oxidative dehydrogenation of ethane (ODE) was carried out in a catalytic membrane reactor-distributor on a Mo-V-Te-Ox catalyst supported on asymmetric ceramic membranes. The obtained results show the obvious advantages of ODE with the use of a membrane system. Application of the membrane approach allows us to use initial gas mixtures with the O2:C2H6 ratios that are unacceptable for safety reasons in conventional reactors. Under optimal process conditions, the conversion of ethane of 70% can be achieved in a membrane reactor while maintaining the ethylene selectivity in the range of 95–98%.

Ermilova M. , Kucherov A. , Orekhova N. , Finashina E. , Kustov L. , Yaroslavtsev A.
Ethane oxidative dehydrogenation to ethylene in a membrane reactor with asymmetric ceramic membranes
Chemical Engineering and Processing. 2018. V.126. P.150-155. DOI: 10.1016/j.cep.2018.02.011 WOS Scopus OpenAlex

Web of science:	WOS:000430755200016
Scopus:	2-s2.0-85043301945
OpenAlex:	W2791735635

БД	Цитирований
OpenAlex	18
Scopus	11
Web of science	13