Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines

Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2016, Volume: 26, Number: 5, Pages: 413-414 Pages count : 2 DOI: 10.1016/j.mencom.2016.09.016

Authors

Kokorekin Vladimir A. ¹ , Yaubasarova Rauza R. ¹ , Neverov Sergei V. ¹ , Petrosyan Vladimir A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Selective thiocyanation (yield 70–90%) at the 3-position of pyrazolo[1,5-a]pyrimidines was performed with thiocyanogen electrochemically generated in situ from NH4SCN in MeCN on a Pt anode. For substrates with higher oxidation potential addition of Lewis acids was necessary.

Kokorekin V.A. , Yaubasarova R.R. , Neverov S.V. , Petrosyan V.A.
Reactivity of electrogenerated thiocyanogen in the thiocyanation of pyrazolo[1,5-a]pyrimidines
Mendeleev Communications. 2016. V.26. N5. P.413-414. DOI: 10.1016/j.mencom.2016.09.016 WOS Scopus OpenAlex

≡ Web of science:	WOS:000386421500016
≡ Scopus:	2-s2.0-84989204401
≡ OpenAlex:	W2524809444